Membranes & functional finishes

PFC-free / PFAS-free

Also known as: Fluorocarbon-free, C0 chemistry

Textiles and finishes free of per- and polyfluoroalkyl substances (PFAS).

~1 min read By Christian Habert Fact-checked by Clubmartin Textile EditorialAI-assisted Last reviewed: Sources (3)

Description

PFC/PFAS-free denotes textiles free of per- and polyfluoroalkyl substances. PFAS are a class of about 10,000 compounds (PFOA, PFOS, GenX etc.) that are extremely persistent, bioaccumulative and toxic (PBT). In textiles they were used in DWR coatings, fluoropolymer membranes (ePTFE) and non-stick coatings.

Regulation: EU REACH restricts PFOA since 2020 (< 25 ppb), PFHxA since 2024 (< 25 ppb); a universal PFAS restriction proposal is at ECHA since Feb 2023. USA: Maine, California ban PFAS in textiles from 2025-2027. Detection: LC-MS/MS per CEN/TS 15968, LOD < 1 ppb.

Alternatives: C0 DWR based on silicone, wax, paraffin or dendrimer chemistry (Bionic-Finish® Eco, Rudolf RUCO-DRY® ECO, HeiQ Eco Dry). Drawback: shorter service life (typically 20-30 % fewer wash cycles than C8). ePE membranes replace ePTFE (GORE-TEX® ePE, Sympatex®). bluesign® and OEKO-TEX® Standard 100 use PFAS-free as certification criterion.

Properties

Test standardCEN/TS 15968, EU REACH
Typical valuesPFOA/PFHxA < 25 ppb
ApplicationOutdoor, PPE, kids' wear

Related product categories

Sources & references

3
  1. Wikipedia: PFAS Wikipedia — Freie Enzyklopädie https://en.wikipedia.org/wiki/Per-_and_polyfluoroalkyl_substances
  2. bluesign bluesign technologies ag https://www.bluesign.com/
  3. OEKO-TEX OEKO-TEX Association https://www.oeko-tex.com/

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